Ferrous sulfate: physical and chemical properties, production, application

Ferrous sulfate: physical and chemical properties, production, application
Ferrous sulfate: physical and chemical properties, production, application

Video: Ferrous sulfate: physical and chemical properties, production, application

Video: Ferrous sulfate: physical and chemical properties, production, application
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Ferrous sulfate is a chemical compound that is extremely common in nature and widely used in various fields of economic activity. There are divalent and trivalent modifications of this substance. The first variety, also called ferrous sulfate, is an inorganic binary non-volatile compound having the formula FeSO4. Externally, this chemical compound is a transparent crystal hydrates of light greenish-blue color, having a high degree of hygroscopicity and solubility in an aqueous medium. In a vacuum, FeSO4 decomposes with high intensity, complete decomposition occurs at a temperature of about 700°C.

ferrous sulfate
ferrous sulfate

Ferrous sulfate is a widely used reagent that crystallizes from solutions at room temperature in the form of FeSO4∙7H2O heptahydrate, which is a pale blue substance. When stored for a long time, it erodes, turning into a white powdery substance,and in the open air gradually turns yellow due to oxidative processes. The weathering of ferrous sulfate is explained by the fact that in its structure there is one molecule of outer sphere water, which easily leaves the crystal lattice.

Trivalent anhydrous iron sulfate is a light yellow, paramagnetic, extremely hygroscopic monoclinic crystal substance. Capable of forming orthorhombic and hexagonal structural modifications. Trivalent iron sulfate crystallizes well from various solutions in the form of various hydrated compounds containing up to ten water molecules. When slowly heated, it turns into an anhydrous s alt, which decomposes well into hematite and sulfuric anhydrite at a temperature of about 650 ° C. Like many other s alts of triply charged cations, ferrous sulfate forms alums that crystallize in the form of pale purple octahedrons. This substance is a good reducing agent for the Ag+ ion, which has strong oxidizing properties. Ferric sulfate, hydrolyzed by boiling the solution in which it is contained, occurs in nature predominantly in jarosite (mineral).

Anhydrous ferrous sulfate
Anhydrous ferrous sulfate

In industry, this substance is obtained mainly as a by-product in metalworking enterprises from various pickling solutions used to remove scale from steel products. Also, this substance can be isolated by calcining pyrites or marcasite with NaCl in air. Another way to synthesize itis the heating of iron oxide in s alts of sulfuric acid. In laboratory practice, this compound is isolated from Fe(OH)2.

It is of considerable curiosity that iron sulfate was discovered on Mars in 2009 by the Spirit spacecraft, from which scientists concluded that strong oxidative processes are occurring on the surface of the planet. Due to the very low density of this substance, the rover is so deeply bogged down in its deposits that it even touched the deep layers of the Martian soil with part of the hull.

Ferrous sulfate hydrolysis
Ferrous sulfate hydrolysis

On Earth, iron sulfate, due to its ability to hydrolyze, is used along with aluminum alum as a flocculant in the process of drinking water purification. Forming hydroxide flakes, this chemical compound adsorbs many harmful impurities. Also, this substance has found wide application in medicine, where it is used as a therapeutic and prophylactic agent for iron deficiency anemia.

In the agricultural industry, iron sulfate is used for chemical soil reclamation, pest control of cultivated plants, destruction of mosses, lichens, weeds and spores of parasitic fungi. In horticulture, ferrous sulfate is used to feed fruit trees as a catalyst for the formation of chlorophyll. The most sensitive to the lack of this substance are apple, pear, plum and peach.

Industrial Ferrous sulfate is widely used in the textile industry, where it is an important ingredient in inks and various mineral dyes. Alsothis substance is a good wood preservative. Some so-called waste solutions of iron sulfate are processed into insulating materials such as ferron and ferrigypsum, which are a mixture of hydrates of this compound with various fillers.

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